期刊
APPLIED SURFACE SCIENCE
卷 518, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apsusc.2020.146193
关键词
Laser-scribed graphene; Supercapacitor; Binder-free; PEDOT
类别
资金
- Ministry of Science and Technology (MOST) of Taiwan [MOST 104-2113-M-152-001-MY2, MOST 105-2320-B-038-014-]
- CPC Corporation [105-3011]
- Taipei Medical University [TMU102-AE1-B02, TMUTOP103004-2]
- MOST of Taiwan [MOST 107-2221-E-131-009-MY3, MOST 108-2221-E-131-004-MY3]
- Academia Sinica Research Project on Integrated Thematic Project [AS-107-TP-A09]
The rapid development of wearable electronic devices and energy storage devices has increased the demand for flexible, lightweight, and durable supercapacitors. Nevertheless, the cost-effective synthesis of suitable active materials and the facile fabrication of electrodes for energy storage systems remain a challenge for practical applications. In this study, we developed a scalable method for the fabrication of graphene-based supercapacitors, by using a CO(2 )infrared laser to transform polyimide (PI) films into porous graphene. Furthermore, when modified with oxidatively polymerized poly (3,4-ethylenedioxythiophene) (PEDOT), the conductivity of the graphene films was enhanced significantly. The resultant films could be fabricated directly for use in supercapacitors without employing metallic current collectors. The current collector-free supercapacitors exhibited excellent electrochemical properties, rivaling those obtained from corresponding devices featuring metallic current electrodes. An assembled device having a large working area (4 x 4 cm(2)) displayed reversible capacities of 115.2, 97.0, and 78.4 F/g at rates of 0.5, 2, and 6 A/g, respectively. Moreover, only slight losses in capacitance occurred after 4000 charge/discharge cycles and 2000 bending cycles, indicative of remarkable cycling life and mechanical stability.
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