期刊
APPLIED CATALYSIS B-ENVIRONMENTAL
卷 270, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.apcatb.2020.118908
关键词
Porous metal-porphyrin triazine-based frameworks; Electrocatalysis; CO2 reduction reaction; CO Production
资金
- National Natural Science Foundation of China [21922811, 51702284, 21878270]
- Zhejiang Provincial Natural Science Foundation of China [LR19B060002]
- Fundamental Research Funds for the Central Universities
- Startup Foundation for Hundred-Talent Program of Zhejiang University
- Australian Research Council [DP170104264]
Electrochemical reduction of CO2 (ECR-CO2) into high value-added products plays a crucial role in energy conversions. Herein, we developed a family of porous metal-porphyrin triazine-based frameworks (MPTFs-x, M = Mn, Fe, Co, Ni, and Cu, x = temperature) with a specific surface area up to 977 m(2) g(-1) and homogenously dispersed transition-metals. Benefiting from a high content of N species of 8.43 at.% and abundantly exposed Ni-N-x active sites, NiPTFs-600 displayed a superb Faradaic efficiency (FE) of CO production (> 90 %) in the range of -0.55 V to -0.95 V with the maximum FE of 97.6 % and current density of 10.8 mA cm(-2) at -0.8 V. The reaction mechanism was found to be the adsorption of CO2 molecules to form *CO2 intermediates, accompanied by successive protonation to produce *COOH and then *CO.
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