期刊
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION
卷 60, 期 2, 页码 550-565出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/anie.202008729
关键词
alkenes; alkynes; hydrosilylation; silanes
资金
- National Key Research and Development Program of China [2017YFA0403103]
- Chinese Academy of Sciences, Key Research Program of Frontier Sciences of CAS [QYZDJ-SSW-SLH051]
- Youth Innovation Promotion Association [2019409]
- State of Mecklenburg-Western Pomerania
- Federal State of Germany (BMBF)
- EU (ERC Advanced Grant NoNaCat)
- Coordenacao de Aperfeicoamento de Pessoal de Nivel Superior-Brasil (CAPES) [001]
- Projekt DEAL
- Light of West China
This minireview discusses the use of homogeneous noble metal catalysts and earth-abundant transition metals/heterogeneous catalysts in hydrosilylation reactions, highlighting the growing interest in more sustainable and economic catalysts.
Hydrosilylation reactions, which allow the addition of Si-H to C=C/C equivalent to C bonds, are typically catalyzed by homogeneous noble metal catalysts (Pt, Rh, Ir, and Ru). Although excellent activity and selectivity can be obtained, the price, purification, and metal residues of these precious catalysts are problems in the silicone industry. Thus, a strong interest in more sustainable catalysts and for more economic processes exists. In this respect, recently disclosed hydrosilylations using catalysts based on earth-abundant transition metals, for example, Fe, Co, Ni, and Mn, and heterogeneous catalysts (supported nanoparticles and single-atom sites) are noteworthy. This minireview describes the recent advances in this field.
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