期刊
CHINESE JOURNAL OF CHEMISTRY
卷 34, 期 12, 页码 1251-1254出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201600417
关键词
alpha-halomethylketone; haloalkyne; catalyzed; hydration; alpha-halogenation
资金
- Planned Science and Technology Project of Hunan Province, China [2015WK3003]
A general atom-economical approach for the synthesis of alpha-halomethyl ketones is demonstrated through Ce(SO4)(2)/acid co-catalyzed hydration of a wide range of haloalkynes. The reactions are conducted under convenient conditions and provide products with excellent regioselectivity in good to excellent yields, with broad substrate scope. This protocol is an alternative to conventional alpha-halogenation of ketones.
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