期刊
CHINESE JOURNAL OF CHEMISTRY
卷 34, 期 11, 页码 1071-1075出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201600357
关键词
aggregation-induced emission; aldehyde group; organic luminescent materials; mechanism; hydrogen-bonding
资金
- National Basic Research Program of China (973 Program) [2013CB834704]
- National Natural Science Foundation of China [51328302, 21404010, 51073026, 51061160500]
In order to get an easy way to achieve the transformation from aggregation-caused quenching luminophores (ACQphores) to aggregation-induced emission luminogens (AIEgens), we took aldehyde groups as the modifying group to decorate anthracene. The fluorescence performances of 9-anthraldehyde (AnA) and 9,10-anthracenedi-carboxaldehyde (AnDA) in solution and aggregated state were studied. We found out that the aldehyde group can transform anthracene with aggregation-caused quenching properties to AIEgen. The single-crystal structures analysis of AnA and AnDA showed that their structure characteristics are responsible for the AIE properties of AnA and AnDA. On one hand, the aldehyde group can cause steric effects to lower intermolecular pi-pi packing style in aggregated state. On the other hand, intermolecular H-bonding interactions can restrict the intramolecular rotation and suppress internal charge transfer. These results may supply a new simple method for the transformation from ACQphores to AIEgens on the point of the molecular design.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据