期刊
ADVANCED SYNTHESIS & CATALYSIS
卷 362, 期 16, 页码 3407-3415出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adsc.202000597
关键词
Diversity-oriented synthesis; 1,6-addition; aldol reaction; vinylogous Michael addition; Spiro and fused systems
资金
- Ministry of Science and Technology of the Republic of China [MOST 107-2628-M-003-001-MY3]
An organobase-controlled, divergent cascade reaction to construct spirocyclohexene indane-1,3-diones and coumarin-fused cyclopentanes is reported. The cascade reaction is triggered by the 1,6-addition of 3-homoacylcoumarins to the indanedione-derived acceptors and further regio/chemoselective reaction that preferentially resulted in spiro systems and fused cyclopentanes in a diversity-oriented manner. The 1,6-addition/aldol and 1,6-addition/vinylogous Michael addition cascade processes were controlled by different base/solvent systems to the predominant formation of one of the two carbocyclic compounds.
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