期刊
ADVANCED MATERIALS
卷 32, 期 37, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/adma.202001259
关键词
high ionic conductivity; lithium-metal batteries; metal-organic frameworks; solid polymer electrolytes; super toughness
类别
资金
- National Natural Science Foundation of China [21771018, 21875004]
- Beijing University of Chemical Technology [buctrc201901]
- Ministry of Foreign Affairs and International Cooperation, Italy (NSFC-MAECI) [51861135202]
- National Key Research and Development Project [2018YFB1502401, 2018YFA0702002]
- Royal Society
- Newton Fund through the Newton Advanced Fellowship award [NAF\R1\191294]
- Program for Changjiang Scholars and Innovation Research Team in the University [IRT1205]
- Fundamental Research Funds for the Central Universities
- Ministry of Finance
- Ministry of Education of PRC
Lithium-metal batteries (LMBs) with high energy densities are highly desirable for energy storage, but generally suffer from dendrite growth and side reactions in liquid electrolytes; thus the need for solid electrolytes with high mechanical strength, ionic conductivity, and compatible interface arises. Herein, a thiol-branched solid polymer electrolyte (SPE) is introduced featuring high Li(+)conductivity (2.26 x 10(-4)S cm(-1)at room temperature) and good mechanical strength (9.4 MPa)/toughness (approximate to 500%), thus unblocking the tradeoff between ionic conductivity and mechanical robustness in polymer electrolytes. The SPE (denoted as M-S-PEGDA) is fabricated by covalently cross-linking metal-organic frameworks (MOFs), tetrakis (3-mercaptopropionic acid) pentaerythritol (PETMP), and poly(ethylene glycol) diacrylate (PEGDA) via multiple C-S-C bonds. The SPE also exhibits a high electrochemical window (>5.4 V), low interfacial impedance (<550 omega), and impressive Li(+)transference number (t(Li+)= 0.44). As a result, Li||Li symmetrical cells with the thiol-branched SPE displayed a high stability in a >1300 h cycling test. Moreover, a Li|M-S-PEGDA|LiFePO(4)full cell demonstrates discharge capacity of 143.7 mAh g(-1)and maintains 85.6% after 500 cycles at 0.5 C, displaying one of the most outstanding performances for SPEs to date.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据