Room-temperature phosphorescence from purely organic materials

Room-temperature phosphorescence (RTP) materials have attracted great attention due to their involvement of excited triplet states and comparatively long decay lifetimes. In this short review, recent progress on enhancement of RTP from purely organic materials is summarized. According to the mechanism of phosphorescence emission, two principles are discussed to construct efficient RTP materials: one is promoting intersystem crossing (ISC) efficiency by using aromatic carbonyl, heavy atom, or/and heterocycle/heteroatom containing compounds; the other is suppressing intramolecular motion and intermolecular collision which can quench excited triplet states, including embedding phosphors into polymers and packing them tightly in crystals. With aforementioned strategies, RTP from purely organic materials was achieved both in fluid and rigid media. (C) 2016 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.