期刊
ACS APPLIED MATERIALS & INTERFACES
卷 12, 期 27, 页码 30438-30448出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsami.0c07803
关键词
lithium-ion battery; degradation; battery safety; lithium plating; in operando detection and mapping
资金
- Office of Naval Research (ONR) as part of the NURP program [N00014-17-1-2942]
Existing in operando methods for detection of plated lithium can only detect the presence of plating after the charge is complete and irreversible damage has already occurred. In this work, the characteristic potential minimum on the graphite electrode during high rate lithiation is proposed and assessed as an in operando technique for detecting the onset of lithium plating. While other studies have shown that rapid self-heating of a cell can cause this type of voltage overshoot, we confirm through temperature-controlled coin cell experiments that such a voltage profile can also be caused by the occurrence of severe lithium plating. In cells which demonstrated voltage overshoot, macroscopically observable lithium plating films were present on the graphite electrodes upon disassembly, resulting in very poor single-cycle Coulombic efficiency. The significance of this voltage characteristic is confirmed through direct observation of the onset of lithium plating in an in situ optical microscopy cell. We observe that the growth of large metallic lithium deposits within the porous electrode structure can cause swelling and cracking of the graphite electrode, suggesting loss of active material due to mechanical electrode degradation as an important consequence of severe lithium plating.
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