期刊
ACS OMEGA
卷 5, 期 21, 页码 12067-12072出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsomega.0c00276
关键词
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资金
- National Natural Science Foundation of China [11564023, 51904137]
- Yunnan local University Joint Special Funds for Basic Research [2017FH001-007, 2018FH001-017]
- Applied Basic Research Projects of Yunnan Province [2019FD044]
- Scientific Research Fund of Yunnan Education Department [2019J0563, 2019J0564, 2020Y0464]
Cocrystallization has been applied widely for material synthesis. Recently cocrystal of organic molecules has been developing rapidly, taking the advantages of the flexibility and self-assembly of organic molecules. Here we report an experimental study of a cocrystal of copper-phthalocyanines and fluorinated ones. We have grown the samples via the vapor-phase deposition of the mixture with different mass ratios from 1:13.5 to 6:1. As suggested by our scanning electron microscopy (SEM), X-ray diffraction (XRD), and Raman spectroscopy, new crystal structures and morphologies through our novel strategy for the cocrystallization of these molecules have been found. Our work will provide a solid foundation to systematically synthesize the cocrystal of phthalocyanine molecules with new crystal structures, thus providing the opportunity to advance material properties.
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