期刊
BIOMASS CONVERSION AND BIOREFINERY
卷 12, 期 7, 页码 2377-2387出版社
SPRINGER HEIDELBERG
DOI: 10.1007/s13399-020-00766-2
关键词
Low-cost biomaterials; Apricot shells; Modification; Surface; characterization
资金
- Serbian Ministry of Education, Science and Technological Development [TR 31003]
Alkali modification of apricot shells increased porosity and total surface area, as well as crystallite size and crystallinity index. Although the cellulose-rich fraction from the modified sample exhibited higher thermal stability, overall thermal analysis indicated lower thermal stability of the alkali-modified biomass. This suggests that this modification can enhance the fuel properties of apricot shell biomass and has potential applications in energy recovery.
A low-cost waste biomass generated from a food industry, apricot shells, was subjected to alkali modification in order to compare morphology, crystalline structure and thermal stability of native and modified biomass, accompanied by their cellulose-rich fractions. The surface morphology and structure of compared samples were analysed by the scanning electron microscopy (SEM) and mercury porosimetry. Furthermore, Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD) and thermal analysis (TG/DTA) were applied. The results have shown that after alkaline treatment, inter- and intra-particle porosity in the material rises, resulting in increase of the total surface area. The XRD diffractograms showed that crystallinity index increased together with crystallite size, suggesting that modified sample has more ordered crystalline structure than native sample (also confirmed by the FTIR analysis). Although the cellulose-rich fraction extracted from the alkali-modified sample showed higher thermal stability, the overall thermal analysis revealed that alkali-modified biomass has lower thermal stability than the native sample. This indicates that this type of modification will improve the fuel properties of this lignocellulosic biomass and imply its possible application in energy recovery process.
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