期刊
CHEMSUSCHEM
卷 9, 期 15, 页码 1916-1920出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cssc.201600521
关键词
carbamates; carbon dioxide; chemoselective; peptides; protecting group
资金
- Fonds der Chemischen Industrie (FCI), Liebig-Fellowship
Synthesis of carbamates directly from amines using CO2 as the carbon source is a straightforward and sustainable approach. Herein, we describe a highly effective and chemoselective methodology for the synthesis of carbamates at room temperature and atmospheric pressure. This methodology can also be applied to protect the amino group in amino acids and peptides, and also to synthesize important pharmaceuticals.
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