期刊
CATALYSTS
卷 10, 期 4, 页码 -出版社
MDPI
DOI: 10.3390/catal10040420
关键词
waste-derived synthesis gas; high-temperature water-gas shift; Co-CeO2 catalyst; preparation method; oxygen vacancy
资金
- National Research Foundation of Korea (NRF) - Korean government (MSIT) [2020R1A2B5B01002346]
Waste to energy technology is attracting attention to overcome the upcoming environmental and energy issues. One of the key-steps is the water-gas shift (WGS) reaction, which can convert the waste-derived synthesis gas (H-2 and CO) to pure hydrogen. Co-CeO2 catalysts were synthesized by the different methods to derive the optimal synthetic method and to investigate the effect of the preparation method on the physicochemical characteristics of Co-CeO2 catalysts in the high-temperature water-gas shift (HTS) reaction. The Co-CeO2 catalyst synthesized by the sol-gel method featured a strong metal to support interaction and the largest number of oxygen vacancies compared to other catalysts, which affects the catalytic activity. As a result, the Co-CeO2 catalyst synthesized by the sol-gel method exhibited the highest WGS activity among the prepared catalysts, even in severe conditions (high CO concentration: similar to 38% in dry basis and high gas hourly space velocity: 143,000 h(-1)).
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