4.6 Article

Carbon foam with microporous structure for high performance symmetric potassium dual-ion capacitor

期刊

JOURNAL OF ENERGY CHEMISTRY
卷 43, 期 -, 页码 129-138

出版社

ELSEVIER
DOI: 10.1016/j.jechem.2019.08.013

关键词

Carbon foam; Symmetric potassium-based dual-ion capacitor; High energy power density; Ultrafast charge and slow discharge

资金

  1. National Natural Science Foundation of China [51672078, 21473052]
  2. Hunan University State Key Laboratory of Advanced Design and Manufacturing for Vehicle Body Independent Research Project [71675004]
  3. Fundamental Research Funds for the Central Universities
  4. Hunan Natural Science Foundation [2019JJ40031]
  5. Foundation of State Key Laboratory of Coal Conversion [J1718-903]

向作者/读者索取更多资源

A novel carbon foam with microporous structure (CFMS), with the advantages of a simple fabrication process, low energy consumption, large specific surface area and high conductivity, has been prepared by a facile one-step carbonization. In addition, the carbon foam possesses suitable interlayer spacing in short range which is flexible to accommodate the deformation of carbon layer caused by the ion insertion and deinsertion at the charge and discharge state. Furthermore, a low cost carbon-based symmetric potassium dual-ion capacitor (PDIC), which integrates the virtues of potassium ion capacitors and dual-ion batteries, is successfully established with CFMS as both the battery-type cathode and the capacitor-type anode. PDIC displays a superior rate performance, an ultra-long cycle life (90% retention after 10000 cycles), and a high power density of 7800W kg(-1) at an energy density of 39 Wh kg(-1). The PDIC also exhibits excellent ultrafast charge and slow discharge properties, with a full charge in just 60 s and a discharge time of more than 3000 s. (C) 2019 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.

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