期刊
POLYMERS
卷 12, 期 5, 页码 -出版社
MDPI
DOI: 10.3390/polym12051102
关键词
fluoroquinolones; ultrasound radiation; mesoporous carbon; desirability function; thermodynamics; wastewater; cost analysis
资金
- University of Johannesburg, South Africa (Department of Chemical Sciences)
- National Research Foundation (South Africa) [91230, 99270]
The application of a magnetic mesoporous carbon/beta -cyclodextrin-chitosan (MMPC/Cyc-Chit) nanocomposite for the adsorptive removal of danofloxacin (DANO), enrofloxacin (ENRO) and levofloxacin (LEVO) from aqueous and environmental samples is reported in this study. The morphology and surface characteristics of the magnetic nanocomposite were investigated by X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET) adsorption-desorption and Fourier transform infrared spectroscopy (FTIR). The N-2 adsorption-desorption results revealed that the prepared nanocomposite was mesoporous and the BET surface area was 1435 m(2) g(-1). The equilibrium data for adsorption isotherms were analyzed using two and three isotherm parameters. Based on the correlation coefficients (R-2), the Langmuir and Sips isotherm described the data better than others. The maximum monolayer adsorption capacities of MMPC/Cyc-Chit nanocomposite for DANO, ENRO and LEVO were 130, 195 and 165 mg g(-1), respectively. Adsorption thermodynamic studies performed proved that the adsorption process was endothermic and was dominated by chemisorption.
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