期刊
ACS MACRO LETTERS
卷 9, 期 4, 页码 500-506出版社
AMER CHEMICAL SOC
DOI: 10.1021/acsmacrolett.0c00142
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资金
- Joint Center for Energy Storage Research (JCESR), an Energy Innovation Hub - U.S. Department of Energy, Office of Science, Basic Energy Sciences (BES) [DE-AC02-06CH11357]
- National Science Foundation Division of Materials Research [1609076]
- Direct For Mathematical & Physical Scien
- Division Of Materials Research [1609076] Funding Source: National Science Foundation
Cross-linked polymer electrolytes containing structurally dynamic disulfide bonds have been synthesized to investigate their combined ion transport and adhesive properties. Dynamic network polymers of varying cross-link densities are synthesized via thiol oxidation of a bisthiol monomer, 2,2'-(ethylenedioxy)diethanethiol, and tetrathiol cross-linker, pentaerythritol tetrakis(3-mercaptopropionate). At optimal loading of lithium bis(trifluoromethane-sulfonyl-imide) (LiTFSI) salt, the ionic conductivities (sigma) at 90 degrees C are about 1 x 10(-4) and 1 x 10(-5) S/cm at the lowest and highest cross-linking, respectively. Notably, in comparison to the equivalent nondynamic network, the dynamic network shows a positive deviation in sigma above 90 degrees C, which suggests the enhancement of ion transport occurs from the difference in structural relaxation on account of the dissociation of disulfide bonds. Lap shear adhesion and conductivity tests on ITO-coated glass substrates reveal the dynamic network exhibits a higher adhesive shear strength of 0.2 MPa (vs 0.03 MPa for the nondynamic network) and higher a after the application of external stimulus (UV light or heat). The adhesive strength and sigma are stable over multiple debonding/rebonding cycles and, thus, demonstrating the utility of these structurally dynamic networks as solid polymer electrolyte adhesives.
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