期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 11, 期 23, 页码 3345-3349出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601290
关键词
arylation; C-C coupling; diaryliodonium salt; heterocycles; homogeneous catalysis
资金
- DBT, New Delhi
- CSIR, New Delhi
Easily accessible heteroaromatic carboxylic acids and diaryliodonium salts were successfully employed to construct valuable 2-arylindoles and heteroaryl carboxylates in a regioselective fashion. C2-arylated indoles were produced using a Pd-catalyzed decarboxylative strategy in water without any base, oxidant, or ligand. Heteroaryl carboxylates were prepared under metal and base-free conditions. This protocol was successfully utilized to synthesize Paullone, a cyclin-dependent kinase (CDK) inhibitor.
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