期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 12, 期 2, 页码 212-215出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601571
关键词
allylic alkylation; asymmetric catalysis; carbanions; palladium; Thorpe reaction
资金
- National Natural Science Foundation of China (NSFC) [21532010, 21372242, 21472214, 21421091]
- NSFC
- Research Grants Council of Hong Kong Joint Research Scheme [21361162001]
- Strategic Priority Research Program of the Chinese Academy of Sciences [XDB20000000]
- Technology Commission of Shanghai Municipality
- Croucher Foundation of Hong Kong
A new type of nucleophile, a 3-imino nitrile carbanion generated in situ by Thorpe reaction of acetonitrile with a base, was developed successfully and applied in a Pd-catalyzed asymmetric allylic alkylation with mono-substituted allyl reagents under Pd/SIOCPhox catalysis, affording beta-enaminonitrile products in high yields with excellent regio- and enantioselectivities.
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