期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 11, 期 11, 页码 1668-1671出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201600222
关键词
aromaticity; carbon catalyst; dehydrogenation; heterogeneous catalysis; nanocatalysis
资金
- NSFC of China [21573255, 21133010, 51221264]
- Chinese Academy of Sciences [XDA09030103]
- Special Program for Applied Research on Super Computation of the NSFC-Guangdong Joint Fund
- Institute of Metal Research [Y3NBA211A1]
It is believed that the oxygen groups on the carbon catalysts are responsible for the observed reactivity for C-H bond activations. On the other hand, the oxygen groups also reduce the aromaticity of the host. The loss of the aromaticity increases reactivities of the carbon atoms and they become the active sites for the C-H bond activation. The newly identified C-C site exhibits the comparable catalytic performance in the oxidative dehydrogenation (ODH) of propane compared with the conventional oxygen groups like quinone and ketone. A series of calculations indicate that the aromaticity might be a useful descriptor for the carbon catalysts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据