期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 12, 期 1, 页码 31-35出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201601452
关键词
absolute configuration; cations; chiroptical methods; helicenes; radicals
资金
- Deutsche Forschungsgemeinschaft (DFG) [SFB 953]
- European Community [PIRSES-GA-2012-318930 - InTechSE]
A stable chiral hetero[4] helicene radical cation was synthesized and characterized by UV/Vis absorption and EPR spectroscopy, as well as X-ray crystallography. For the first time, a combination of chiroptical methods involving ECD, ORD, and VCD, supported by quantum mechanical predictions, enabled the elucidation of the absolute configuration of such open-shell helical species.
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