期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 27, 页码 9135-9138出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601597
关键词
amidation; cobalt; quinoline; sp(3) C-H activation
资金
- SERB [EMR/2016/000136]
- CSIR
An efficient and external oxidant-free, Cp*Co-III-catalyzed C(sp(3))-H bond amidation of 8-methylquinoline, using oxazolone as an efficient amidating agent, is reported for the first time under mild conditions. The reaction is selective and tolerates a variety of functional groups. Based on previous reports and experimental results, the deprotonation pathway proceeds through an external base-assisted concerted metalation and deprotonation process.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据