期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 40, 页码 14151-14154出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603092
关键词
C-H activation; nickel; reaction mechanisms; selenylation; sulfenylation
资金
- European Research Council under the European Community [307535]
The C-H thiolation of aniline derivatives was accomplished with a versatile nickel(II) catalyst under ligand-free conditions. The robust nature of the nickel catalysis system was reflected by the C-H thiolation with a good functional group tolerance and an ample scope, employing anilines possessing removable directing groups. The widely applicable nickel catalyst also allowed for aniline C-H selenylations, while mechanistic studies provided strong support that the rate-determining step is the C-H activation.
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