期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 10, 页码 3292-3295出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201504985
关键词
acylation; cyclization; oxindole; photoredox catalysis; synthetic methods
资金
- European Commission [H2020-MSCA-IF-2014, 660668]
- Swedish NMR Centre at the University of Gothenburg
- Marie Curie Actions (MSCA) [660668] Funding Source: Marie Curie Actions (MSCA)
A novel method for the mild photoredox-mediated tandem radical acylarylation and tandem acylation/semipinacol rearrangement has been developed. The synthesis of highly functionalized ketones bearing all-carbon - or -quaternary centers has been achieved using easily available symmetric aromatic carboxylic anhydrides as the acyl radical source. The method allows for a straightforward introduction of the keto functionality and concomitant construction of molecular complexity in a single operation.
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