期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 28, 页码 9546-9550出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601819
关键词
alkenes; catalyst-free reactions; debromination; Hantzsch ester; visible light
资金
- National Science Foundation of China [21572099, 21332005]
- Natural Science Foundation of Jiangsu Province [BK20151379]
- Ph.D. Programs Foundation of the Ministry of Education of China [20130091120047]
- SRF for the Returned Overseas Chinese Scholars (ROCS), State Education Ministry (SEM)
The debromination of vicinal dibromo compounds to generate alkenes usually requires harsh reaction conditions and the addition of catalysts. Just recently the visible-light-induced debromination of vicinal dibromo compounds emerged as a possible alternative to commonly used methods, but the substrate scope of this reaction is limited and a photocatalyst is necessary for the successful conversion of the starting compounds. A catalyst-free visible-light-induced debromination of vicinal dibromo compounds with a base-activated Hantzsch ester as photosensitizer is reported. The method has a wide substrate scope and a broad functional-group compatibility.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据