期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 16, 页码 5547-5550出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201600661
关键词
copper; demethylation; oxygen; sulfonimidamides; sulfoximines
资金
- China Scholarship Council (CSC)
- Alexander von Humboldt Foundation
Under an atmosphere of dioxygen, copper-catalyzed de-alkylation/amination sequences provide sulfonimidamides from unprotected sulfoximines in moderate to good yields. Mechanistic studies suggest the involvement of radicals in both the C-S bond cleavage and the formation of the new N-S bond.
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