期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 25, 页码 8694-8699出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601000
关键词
alkyl sulfinates; photocatalysis; reaction mechanisms; transient spectroscopy; vinyl sulfones
资金
- German Science Foundation (DFG) [GRK 1626]
- Fonds der Chemischen Industrie
- Czech Ministry of Education, Youth and Sports [LO1214, LM2015051]
- Czech Science Foundation [14-09190S]
Alkyl- and aryl vinyl sulfones were obtained by eosin Y (EY)-mediated visible-light photooxidation of sulfinate salts and the reaction of the resulting S-centered radicals with alkenes. Optimized reaction conditions, the sulfinate and alkene scope, and X-ray structural analyses of several reaction products are provided. A detailed spectroscopic study explains the reaction mechanism, which proceeds through the EY radical cation as key intermediate oxidizing the sulfinate salts.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据