期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 23, 期 1, 页码 214-218出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604972
关键词
fullerene; metal-organic frameworks; pyrene; singlet oxygen; sulfur mustard
资金
- Army Research Office [W911NF-13-1-0229]
- Joint Science and Technology Office for Chemical and Biological Defense (JSTO-CBD) [BA13PHM210]
- Deanship of Scientific Research (DSR), King Abdulaziz University, Jeddah [23-130-36-HiCi]
- NSERC
A fullerene-based photosensitizer is incorporated postsynthetically into a Zr-6 -based MOF, NU-1000, for enhanced singlet oxygen production. The structural organic linkers in the MOF platform also act as photosensitizers which contribute to the overall generation of singlet oxygen from the material under UV irradiation. The singlet oxygen generated by the MOF/fullerene material is shown to oxidize sulfur mustard selectively to the less toxic bis(2-chloroethyl)sulfoxide with a half-life of only 11 min.
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