期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 33, 页码 11574-11577出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602753
关键词
aromatic compounds; boronate; borylation; electrophilic substitution
资金
- Ministry of Education, Culture, Sports, Science & Technology in Japan (MEXT) [15H01004, 26288095]
- Accelerated Innovation Research Initiative Turning Top Science and Ideas into High-Impact Values (ACCEL) program from the Japan Science and Technology Agency (JST)
- Grants-in-Aid for Scientific Research [15H01004, 16J02975, 26288095] Funding Source: KAKEN
A demethylative direct borylation is reported, which was applied to the synthesis of benzo[fg] tetracenes containing boronate ester, amide, and thioester substructures. Depending on the heteroatom adjacent to boron, the molecules showed characteristic photophysical properties, molecular arrangements, and chemical stabilities. The key to the successful synthesis is the appropriate choice of the boron source and Bronsted base. The versatility of the direct borylation was demonstrated by the synthesis of a boronate-based benzo[hi] hexacene.
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