期刊
ADVANCED ENERGY MATERIALS
卷 10, 期 25, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.201904026
关键词
cycle stability; functional coating layers; lithium-sulfur batteries; shuttle effects; volume change
类别
资金
- National Natural Science Foundation of China [21875065, 51673064]
- International Science AMP
- Technology Cooperation Program of China [2016YFE0131200]
The shuttle of polysulfide and severe volume change of sulfur cathodes, are the bottlenecks in the practical application of lithium-sulfur batteries, and need to be solved through further exploration of simple and scalable strategies. Herein, an elastic and conductive coating layer is designed and synthesized, by combining water soluble conducting polymer modified carbon nanotubes (PASANTs) with crosslinked waterborne polyurethane (cWPU). It shows high electronic conductivity and excellent resilience. As a result, a lithium-sulfur battery with cWPU/PASANTs coated cathode is able to achieve an outstanding cycle stability with a capacity of 70.8% after 500 cycles at 0.5C and an excellent rate performance (specific capacity of 1130 mAh g(-1) at 0.1C and maintain 68.2% at 2C). This work embodies a systematic design concept, which shows the application prospects of large-scale production, and is expected to be further applied to other easily pulverized high-specific-capacity materials such as silicon and tin.
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