期刊
ADVANCED ENERGY MATERIALS
卷 10, 期 22, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/aenm.202000081
关键词
2D heterostructures; V2O5; graphene; zinc ion batteries
类别
资金
- National Natural Science Foundation of China [51572259, 51872283, 21805273]
- National Key R&D Program of China [2016YFA0200200]
- LiaoNing Revitalization Talents Program [XLYC1807153]
- Joint Research Fund Liaoning-Shenyang National Laboratory for Materials Science [20180510038]
- DICP [DICP ZZBS201708, DICP ZZBS201802]
- DICPQIBEBT [DICPQIBEBT UN201702]
- Dalian National Laboratory For Clean Energy (DNL) of CAS
- DNL Cooperation Fund
- CAS [DNL180310, DNL180308, DNL201912, DNL201915]
- Natural Science Foundation of Liaoning Province
Rechargeable aqueous zinc-ion batteries (ZIBs) are appealing due to their high safety, zinc abundance, and low cost. However, developing suitable cathode materials remains a great challenge. Herein, a novel 2D heterostructure of ultrathin amorphous vanadium pentoxide uniformly grown on graphene (A-V2O5/G) with a very short ion diffusion pathway, abundant active sites, high electrical conductivity, and exceptional structural stability, is demonstrated for highly reversible aqueous ZIBs (A-V2O5/G-ZIBs), coupling with unprecedented high capacity, rate capability, long-term cyclability, and excellent safety. As a result, 2D A-V2O5/G heterostructures for stacked ZIBs at 0.1 A g(-1) display an ultrahigh capacity of 489 mAh g(-1), outperforming all reported ZIBs, with an admirable rate capability of 123 mAh g(-1) even at 70 A g(-1). Furthermore, the new-concept prototype planar miniaturized zinc-ion microbatteries (A-V2O5/G-ZIMBs), demonstrate a high volumetric capacity of 20 mAh cm(-3) at 1 mA cm(-2), long cyclability; holding high capacity retention of 80% after 3500 cycles, and in-series integration, demonstrative of great potential for highly-safe microsized power sources. Therefore, the exploration of such 2D heterostructure materials with strong synergy is a reliable strategy for developing safe and high-performance energy storage devices.
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