期刊
ACS CATALYSIS
卷 10, 期 8, 页码 4671-4676出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c01318
关键词
sp(3) C-H activation; photocatalysis; nickel; enantioselectivity; metallaphotoredox
资金
- China Scholarship Council (CSC)
- European Union [844854]
- National Science Foundation under the CCI Center for Selective C-H Functionalization [CHE-1700982]
- ICIQ
- [FEDER/MCI-AEI/PGC2018-096839-B-I00]
- Marie Curie Actions (MSCA) [844854] Funding Source: Marie Curie Actions (MSCA)
A dual catalytic sp(3) alpha C-H arylation and alkylation of benzamides with organic halides is described. This protocol exhibits an exquisite site selectivity, chemoselectivity, and enantioselectivity pattern, offering a complementary reactivity mode to existing sp(3) arylation or alkylations via transition metal catalysis or photoredox events.
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