期刊
ACS CATALYSIS
卷 10, 期 9, 页码 5250-5260出版社
AMER CHEMICAL SOC
DOI: 10.1021/acscatal.0c01184
关键词
CO2 hydrogenation; Cs-promoted CuFeZn catalyst; higher alcohols; synergistic catalysis; tandem pathway
资金
- National Natural Science Foundation of China [21872106, 21603244]
- China National Key Research and Development Plan Project [2018YFB1502000]
- Fundamental Research Funds for Central Universities [2042019kf0019, 2042019kf022]
Higher alcohol (C2+) synthesis (HAS) from direct CO2 hydrogenation is a promising way to realize the fixation of CO2 to high-value chemicals; however, the identification of active catalysts to give satisfactory activity and selectivity is not yet achieved, let alone the elucidation of mechanism. Here, we report a working catalyst containing Cu-Fe-Zn that can efficiently and selectively synthesize C-2(+) alcohols from CO2 hydrogenation. The optimized catalyst-encoded CsC(0)(.)(8)F(1.0)Z(1.0) exhibits a high C2+ OH/ROH fraction (weight percent of C-2(+) alcohols in total C-1 and C-2(+) alcohols) of 93.8% with a high C2+OH space time yield (STY) of 73.4 mg g(cat)(-1) h(-1) (1.47 mmol g(cat)(-1) h(-1)).( )A( )mechanism study reveals that HAS experiences a tandem pathway of combining surface CO* formation on Cu-ZnO dual sites with surface hydrocarbon moieties on Cu-Fe7C3 dual sites at their material interfaces. A good balance of dissociative and nondissociative C-O bond activation in synergy results in the high HAS activity of Cs-C(0)(.)(8)F(1.0)Z(1.0).
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