期刊
NATURE COMMUNICATIONS
卷 11, 期 1, 页码 -出版社
NATURE PUBLISHING GROUP
DOI: 10.1038/s41467-020-15216-w
关键词
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资金
- European Research Council (ERC) under the European Union's Horizon 2020 research and innovation program [819698, GrapheneCore2 785219]
- Deutsche Forschungsgemeinschaft (MX-OSMOPED project)
- German Research Foundation (DFG) within the Cluster of Excellence
- Agence Nationale de la Recherche (Label STORE-EX)
- Alexander von Humboldt Foundation
- China Scholarship Council
- U.S. Department of Energy, Office of Science, Basic Energy Sciences, Division of Materials Science and Engineering [DE-AC02-07CH11358]
Employing high-rate ion-intercalation electrodes represents a feasible way to mitigate the inherent trade-off between energy density and power density for electrochemical energy storage devices, but efficient approaches to boost the charge-storage kinetics of electrodes are still needed. Here, we demonstrate a water-incorporation strategy to expand the interlayer gap of alpha-MoO3, in which water molecules take the place of lattice oxygen of alpha-MoO3. Accordingly, the modified alpha-MoO3 electrode exhibits theoretical-value-close specific capacity (963 C g(-1) at 0.1mV s(-1)), greatly improved rate capability (from 4.4% to 40.2% at 100 mVs(-1)) and boosted cycling stability (from 21 to 71% over 600 cycles). A fast-kinetics dual-ion-intercalation energy storage device is further assembled by combining the modified alpha-MoO3 anode with an anion-intercalation graphite cathode, operating well over a wide discharge rate range. Our study sheds light on a promising design strategy of layered materials for high-kinetics charge storage.
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