Synthesis of high-entropy alloy nanoparticles on supports by the fast moving bed pyrolysis

High-entropy alloy nanoparticles (HEA-NPs) are important class of materials with significant technological potential. However, the strategies for synthesizing uniformly dispersed HEA-NPs on granular supports such as carbon materials, gamma -Al2O3, and zeolite, which is vital to their practical applications, are largely unexplored. Herein, we present a fast moving bed pyrolysis strategy to immobilize HEA-NPs on granular supports with a narrow size distribution of 2nm up to denary (MnCoNiCuRhPdSnIrPtAu) HEA-NPs at 923K. Fast moving bed pyrolysis strategy ensures the mixed metal precursors rapidly and simultaneously pyrolyzed at high temperatures, resulting in nuclei with a small size. The representative quinary (FeCoPdIrPt) HEA-NPs exhibit high stability (150h) toward hydrogen evolution reaction with high mass activity, which is 26 times higher than the commercial Pt/C at an overpotential of 100mV. Our strategy provides an improved methodology for synthesizing HEA-NPs on various supports. The large-scale application of extremely small, high-entropy alloy nanoparticles is limited by the phase separation and immobilization. Here, the authors develop a general method of fast-moving bed pyrolysis, uniformly dispersing high-entropy alloy nanoparticles on various granular supports.