期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 9, 页码 2892-2895出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201504511
关键词
carbene; computational chemistry; gold; vinylidene
资金
- DAAD
- Alexander von Humboldt Foundation
We herein report a computational study of the bonding in gold(I) vinylidene complexes and compare them to their carbene and CO analogues. The relevance of these intermediates is analysed for the intramolecular cyclisation leading to vinyl sulfonates.
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