期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 46, 页码 16437-16440出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201604452
关键词
amino acids; cross-coupling; decarboxylation; nickel catalysis; photoredox catalysis
资金
- European Research Council under European Union/ERC [617044]
A mild approach for the decarboxylative aminomethylation of aryl sulfonates by the combination of photoredox and nickel catalysis through C-O bond cleavage is described for the first time. A wide range of aryl triflates as well as aryl mesylates, tosylates and alkenyl triflates afford the corresponding products in good to excellent yields.
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