期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 32, 页码 11461-11468出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602264
关键词
alkaline earth metals; CAAC ligands; C-F activation; C-H activation; non-innocent
资金
- SCG Chemicals Co., Ltd
- Trinity College
A cyclic (alkyl)(amino) carbene (CAAC) was found to undergo unprecedented rearrangements and transformations of its core structure in the presence of Group 1 and 2 metals. Although the carbene was also found to be prone to intramolecular C-H activation, it was competent for intermolecular activation of a variety of sp-, sp(2)-, and sp(3)-hybridized C-H bonds. Double C-F activation of hexafluorobenzene was also observed in this work. These processes all hold relevance to the role of these carbenes in catalysis, as well as to their use in the synthesis of new and unusual main group or transition metal complexes.
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