期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 44, 页码 15654-15658出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603677
关键词
alkyl boronic esters; amides; copper; cross-coupling; NacNac ligand
资金
- University of Delaware (UD)
- NIH [P20GM104316, NSF CHE0421224, CHE1229234, CHE0840401, NIH P20GM104316, P30GM110758, S10RR026962, S10OD016267]
The oxidative copper-catalyzed cross-coupling of functionalized alkyl boronic esters with primary amides is reported. Through the identification of appropriate diketimine ligands, conditions for efficient coupling of both primary and secondary alkyl boronic esters with diverse primary amides, including acetamide, have been developed.
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