期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 46, 页码 16494-16504出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602937
关键词
amino acids; ionic liquid crystals; mesophases; self-assembly; X-ray diffraction
资金
- Deutsche Forschungsgemeinschaft [LA 907/17-1, GI 243/8-1]
- Bundesministerium fur Bildung und Forschung [01 RI05177]
- Fonds der Chemischen Industrie
- Ministerium fur Wissenschaft, Forschung und Kunst des Landes Baden-Wurttemberg
- Gesellschaft Deutscher Chemiker
Synthetic strategies were developed to prepare l-tyrosine-based ionic liquid crystals with structural variations at the carboxylic and phenolic OH groups as well as the amino functionality. Salt metathesis additionally led to counterion variation. The liquid-crystalline properties were investigated by differential scanning calorimetry (DSC), polarizing optical microscopy (POM) and X-ray diffraction (WAXS, SAXS). The symmetrical ILC chlorides bearing the same alkyl chain at both the ester and ether but either an acyclic or cyclic guanidinium group displayed enantiotropic SmA(2) mesophases with phase widths of 31-88K irrespective of the head group. It was particularly the replacement of chloride in the acyclic guanidinium ILC by hexafluorophosphate that induced a phase change from SmA(2) to Col(r). This phase change was attributed to a higher curvature of the interface due to the larger anion, which increased the effective head group cross-sectional area of the amphiphilic ILC. The unsymmetrical acyclic guanidinium chlorides, bearing a constant C-14 ester and variable alkyl chains on the phenolic position, formed enantiotropic SmA(2) phases. The derivative with the largest difference in chain lengths, however, displayed a Col(r) phase, resulting from discoid aggregates of the cone-shaped guanidinium chloride. The results are discussed in terms of the packing parameters, which indicate that the phase behaviour of the thermotropic tyrosine-based ILCs shows analogies to those of lyotropic liquid crystals.
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