期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 44, 页码 15614-15618出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602742
关键词
anisotropic growth; hybrid materials; liquid crystals; luminescence; self-assembly
资金
- EU [FEDER-35477]
- China Scholarship Council (CSC)
- CNRS
Zinc oxide nanoparticles were obtained from the hydrolysis of an organometallic precursor in pure hexadecylamine. Interestingly, we demonstrate that the final (anisotropic or isotropic) shape of the nanoparticles is strongly correlated to the existence of a critical temperature. This suggests that the organization of the fatty amines is a paramount parameter in this synthesis. Moreover, the final hybrid ZnO materials systematically exhibit a liquid-crystal smectic phase, whereas no liquid-crystal phase was observed in the pristine reaction media. This simple process is, therefore, a direct and straightforward method to synthesize liquid-crystal hybrid materials.
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