期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 46, 页码 16415-16419出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201603945
关键词
boranes; density functional theory; insertion; ring expansion; silylenes
资金
- Deutsche Forschungsgeminschaft
Reaction of a N-heterocyclic silylene (NHSi) with PhBX2 (X=Cl, Br) readily afforded six-membered silaborinines through an insertion/ring expansion sequence. Increasing the sterics of the borane from phenyl to duryl enabled the selective generation and isolation of the highly colored silylborane intermediates. Theoretical studies on the mechanism and energetics of the silaborinine formation were fully consistent with the experimental observations.
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