期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 31, 页码 11005-11014出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601406
关键词
carbene ligands; electronic structure; nickel; rhodium; steric hindrance
资金
- Julius-Maximilians-Universitat Wurzburg
- Deutsche Forschungsgemeinschaft (DFG)
N-heterocyclic carbenes (NHCs) and cyclic (alkyl)-(amino)carbenes (CAACs) are of great interest, as their electronic and steric properties provide a unique class of ligands and organocatalysts. Herein, substitution reactions involving novel carbonyl complexes of rhodium and nickel were studied to provide a deeper understanding of the fundamental electronic factors characterizing CAAC(methyl), which were compared with the large array of data available for NHC and sterically more demanding CAAC ligands.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据