期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 30, 页码 10410-10414出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602088
关键词
annulation; carbonylation; catalysis; indoles; rhodium
资金
- NIH [R01M088285]
- NSF [CHE-1464754]
- University of Wisconsin-Madison
- Tianjin Natural Science Foundation [21421001]
- MOE Innovation Teams of China [IRT-13R30, IRT13022]
- Chinese Scholarship Council
- Southern Medical University
- Wisconsin Alumni Research Foundation (WARF)
- UW School of Pharmacy
- Direct For Mathematical & Physical Scien
- Division Of Chemistry [1464754] Funding Source: National Science Foundation
A de novo synthesis of a benzene ring allows for the preparation of a diverse range of heterocycles including indoles, benzofurans, benzothiophenes, carbazoles, and dibenzofurans from simple heteroaryl propargylic esters using a unified carbonylative benzannulation strategy. Multiple substituents can be easily introduced to the C4-C7 positions of indoles and related heterocycles.
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