期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 46, 页码 16356-16398出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201601766
关键词
conjugation; crystal engineering; hydrogen bonds; pi interactions; synthetic methods
资金
- Baku State University
- Foundation for Science and Technology (FCT), Portugal [UID/QUI/00100/2013]
Resonance-assisted hydrogen bonding (RAHB), a concept introduced by Gilli and co-workers in 1989, concerns a kind of intramolecular H-bonding strengthened by a conjugated -system, usually in 6-, 8-, or 10-membered rings. This Review highlights the involvement of RAHB as a driving force in the synthesis of organic, coordination, and organometallic compounds, as a handy tool in the activation of covalent bonds, and in starting moieties for synthetic transformations. The unique roles of RAHB in molecular recognition and switches, E/Z isomeric resolution, racemization and epimerization of amino acids and chiral amino alcohols, solvatochromism, liquid-crystalline compounds, and in synthons for crystal engineering and polymer materials are also discussed. The Review can provide practical guidance for synthetic chemists that are interested in exploring and further developing RAHB-assisted synthesis and design of materials.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据