期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 22, 期 45, 页码 16099-16102出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201602918
关键词
luminescence; organic-inorganic hybrid composites; phosphites; tetradentate ligand; zinc
资金
- Ministry of Science and Technology of Taiwan [MOST 103-2113M-008-011-MY2]
A new 3D tubular zinc phosphite, Zn-2(C22H22N8)(0.5)(HPO3)(2)center dot H2O (1), incorporating a tetradentate organic ligand was synthesized under hydro(solvo) thermal conditions and structurally characterized by single-crystal X-ray diffraction. Compound 1 is the first example of inorganic zincophosphite chains being interlinked through 1,2,4,5-tet-rakis(imidazol-1-ylmethyl) benzene to form a tubular porous framework with unusual organic-inorganic hybrid channels. The thermal and chemical stabilities, high capacity for CO2 adsorption compared to that for N-2 adsorption, and interesting optical properties of LED devices fabricated using this compound were also studied.
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