Effect of amount of TiB2 and B4C particles on tribological behavior of Al7075/B4C/TiB2 mono and hybrid surface composites produced by friction stir processing

In this study, by friction stir processing, we fabricated several defect-free Al7075/B4C/TiB2 mono and hybrid surface composites containing various amounts of B4C and TiB2 reinforcements with high quality interfacial bonding with substrate, fine recrystallized matrix grains, and homogenous dispersion of ceramic particles through the matrix. The composite region of hybrid composite samples was more constricted compared with that of mono composite samples. All hybrid composites had more hardness and wear resistance in comparison to Al/B4C mono composite sample. Among different hybrid composites, the most optimal dispersion of ceramic particles, minimum size of B4C and TiB2 ceramic particles, the lowest friction coefficient, and the highest hardness and wear resistance belonged to the hybrid composite containing equal weight percentage of B4C and TiB2 ceramic particles (named 50%B4C-50%TiB2 hybrid composite). The hardness and wear resistance of the Al7075/B4C, Al7075/TiB2 mono composites and the 50%B4C-50%TiB2 hybrid composite were respectively enhanced by (91%, 121%, 107%) and (67%, 82%, 87%) regarding Al7075 base alloy. During wear, an unstable-simple tribolayer was formed on the surfaces of Al7075 base alloy and unreinforced FSPed samples; however, a more stable mechanically mixed tribolayer containing a mixture of oxygen, ceramic particles, and alloying elements of Al7075 base alloy and steel counterface was formed on the surface of the composite samples. The most stable tribolayer with the highest self-lubricating behavior belonged to the 50%B4C-50%TiB2 hybrid composite owing to the high amount of iron and very low amount of B4C in the tribolayer, resisting the subsurface of tribolayer to crack propagation.