期刊
SURFACE & COATINGS TECHNOLOGY
卷 387, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.surfcoat.2020.125528
关键词
Silicon; Carbon coatings; Anode; Core-shell; Li ion batteries
资金
- Ministry of Science and Technology (MOST), Taiwan, ROC [MOST 108-E-033-MY3, 108-2622-E-033-010-CC3, 109-2911-I-033-502, 109-3116-F-006-018]
In this study, we propose a double core-shell carbon/silicon/graphite composite anode for Li ion batteries. We choose two different sorts of carbon, including crystalline mesocarbon microbeads (MCMB) and amorphous pitch to construct a highly stable carbon matrix to stabilize structural stability of Si during charge and discharge processes. MCMB serves as the core material, by adding nano-sized silicon on the surface to increase reversible capacity and then make a pitch coating as the shell via a high-temperature carbonization process. We try to optimize the content of silicon by 10%, 20%, 30% and 40% onto MCMB. With the increase of silicon content, the reversible capacity is significantly improved. When the silicon content increases to 40%, the reversible capacity begins to decline rapidly. The optimal silicon content in Si/MCMB composite is 30%. The composition-optimized Si/C composite deliver a reversible capacity of 847 mAh/g with a columbic efficiency of 87.8%. After 500 cycles, the capacity still remains at 650 mAh/g with > 79% capacity retention. The results indicate that we demonstrate a silicon/carbon composite with high reversible capacity and good cycle stability.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据