期刊
SMALL
卷 16, 期 23, 页码 -出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/smll.202000952
关键词
Cu2S; hybrid nanosheets; microoctahedra; MoS2; sodium-ion batteries
类别
资金
- National Natural Science Foundation of China [21971145, 21871164, U1764258]
- Taishan Scholar Project Foundation of Shandong Province [ts20190908]
- Natural Science Foundation of Shandong Province [ZR2019MB024]
- Young Scholars Program of Shandong University [2017WLJH15]
Metal sulfides have aroused considerable attention for efficient sodium storage because of their high capacity and decent redox reversibility. However, the poor rate capability and fast capacity decay greatly hinder their practical application in sodium-ion batteries. Herein, a self-template-based strategy is designed to controllably synthesize hierarchical microoctahedra assembled with Cu2S/MoS2 heterojunction nanosheets in the porous carbon framework (Cu2S/MoS2 subset of PCF) via a facile coprecipitation method coupled with vulcanization treatment. The Cu2S/MoS2 subset of PCF microoctahedra with 2D hybrid nanosubunits reasonably integrate several merits including facilitating the diffusion of electrons and Na+ ions, enhancing the electric conductivity, accelerating the ion and charge transfer, and buffering the volume variation. Therefore, the Cu2S/MoS2 subset of PCF composite manifests efficient sodium storage performance with high capacity, long cycling life, and excellent rate capability.
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