期刊
CHEMISTRY OF MATERIALS
卷 28, 期 24, 页码 9064-9076出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.6b04078
关键词
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资金
- BASF SE through the BASF Research Network in Electrochemistry and Batteries
- Natural Sciences and Engineering Council of Canada through their Discovery and Canada Research Chair programs
- Israel Science Foundation (ISF)
We report excellent cycling performance for P2 - Na0.6Li0.2Mn0.8O2 an auspicious cathode material for sodium-ion batteries. This material, which contains mainly Mn4+ exhibits a long voltage plateau on the first charge, similar to that of high-capacity lithium and manganese-rich metal oxides. Electrochemical measurements, X-ray diffraction, and elemental analysis of the cycled electrodes suggest an activation process that includes the extraction of lithium from the material. The activated material delivers a stable, high specific capacity up to similar to 190 mAh/g after 100 cycles in the voltage window between 4.6-2.0 V versus Na/Na+. DFT calculations locate the energy states of oxygen atoms near the Fermi level, suggesting the possible contribution of oxide ions to the redox process. The addition of Li to the lattice improves structural stability compared to many previously reported sodiated transition-metal oxide electrode materials, by inhibiting the detrimental structural transformation ubiquitously observed with sodium manganese oxides during cycling. This research demonstrates the prospect of intercalation materials for Na-ion battery technology that are active based on both cationic and anionic redox moieties.
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