期刊
SCRIPTA MATERIALIA
卷 180, 期 -, 页码 57-61出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.scriptamat.2020.01.021
关键词
Nanocrystalline metal; Grain boundary segregation; Mechanical alloying; Ball mill; Iron alloys
类别
资金
- US Army Research Office [W911NF-14-1-0539]
- US National Science Foundation [DMR-1606914]
- Marie Sklodowska Curie Global Fellowship [740384]
- National Science Foundation [DMR 14-19807]
- National Science Foundation under NSF ECCS award [1541959]
- Marie Curie Actions (MSCA) [740384] Funding Source: Marie Curie Actions (MSCA)
Although mechanical alloying can force immiscible elements into homogeneous solid solution due to its chemically randomizing nature, as microstructure design of powder-processed alloys advances, other alloy configurations are also sought. Here we study ball milling of Fe-Mg alloys and obtain a heterogeneous nanostructure, with grain boundaries decorated by solute even after reaching complete supersaturation and a steady-state grain size. Such nanocrystalline powders having grain boundary segregation in the as-milled state are particularly useful for thermal stability against grain growth. The high diffusivity of Mg is thought to shift the competition between ballistic mixing and equilibration, permitting such a structure to form. (C) 2020 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.
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